Dapsone and iminodibenzyl as novel reagents for the spectrophotometric determination of trace amounts of nitrite in water samples.
نویسندگان
چکیده
A rapid, simple, sensitive and selective spectrophotometric determination of nitrite using new diazotizing and coupling reagents is described. The method is based on a diazotization-coupling reaction between dapsone and iminodibenzyl in a hydrochloric acid medium. The molar absorptivity and Sandell's sensitivity were found to be 7.5 x 10(4) l mol(-1) cm(-1) and 0.000613 microg ml(-1), respectively. The interference effects of various cations and anions were also studied and reported. This method has been found to be applicable for the determination of nitrite in various water samples.
منابع مشابه
KINETIC-SPECTROPHOTOMETRIC DETERMINATION OF TRACE AMOUNTS OF NITRITE BY THE REACTION OF METHYL ORANGE FORMATION
The composite diazotization coupling reaction of sulfanilic acid and N, Ndimethylaniline was used for the precise, accurate, and rapid determination of trace amounts of nitrite ion (0.02-3 µg/ml). The reaction was monitored spectrophotometrically by measuring the absorbance of the produced methyl orange at 510 nm by a fixed the method of 5.0 minutes. The relative standard deviation for the...
متن کاملKinetic-Spectrophotometric Determination of Track Amounts of Nitrite Ion Based on Its Reduction Reaction with Thionine in Acidic Media
A simple, sensitive and rapid method for determination of trace amounts of nitrite ion in real samples is reported. The reaction is initiated by adding known volumes of a nitrite ion solution of identified concentration to acidic solutions of thionine which causes decolorizaiton of reagent with time. The absorbance changes is then monitored spectrophotometrically at l...
متن کاملKinetic spectrophotometric determination of trace amounts of nitrite ion using potassium bromate-murexide mixture in acidic media
A new, simple, rapid, and cheap method for determination of trace amounts of nitrite ion is reported.Determination is based on reduction of bromate ion by nitrite ion, in the presence of murexide inacidic media. During reaction of bromate ion with nitrite ion, the reaction mixture is decolorized.The absorbance changes is then monitored spectrophotometricaly at 520 nm, at 25 °C. Dynamicrange of ...
متن کاملSPECTROPHOTOMETRIC REACTION RATE METHOD FOR THE DETERMINATION OF NITRITE BY CATALYTIC ACTION ON NILE BLUE A BROMATE REACTION
A kinetic method developed for the determination of ultra-trace amounts of nitrite based on its catalytic effect on the reaction between potassium bromate and Nile blue A in strongly acidic media is reported. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of Nile blue A at 645 nm by the fixed-time method. The decrease in absorbance during the first...
متن کاملSynthesis and application of a novel magnetic nanocomposite for determination of trace Cd(II) in water samples
In this work for the first time, Fe3O4@SiO2 core-shell nanoparticles functionalized with isatin groups as a magnetic nanosorbent was applied for the simultaneous extraction of trace amounts of cadmium (II). The characterization of this nanosorbentwas studied using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The effect of seve...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
دوره 17 3 شماره
صفحات -
تاریخ انتشار 2001